Ion exchange plant design some basic principles you will not find here a complete plant design manual. It may also be described as the capacity for a soil to exchange cations for another. This calculator is based on theoretical calculations and explains how to use selectivity coefficients, separation factors and how to determine the maximum volume of water that can be treated with a resin before breakthrough happens. Robert kunin has said, is a unique technology since ft occupies a special place in at least three other scientific. After reading this article you will learn about the cation and anion exchange in soil. Ion exchange is pr obably the most fr equently used chr omatographic technique for the separation and purification of pr oteins, polypeptides, nucleic acids, polynucle otides, and other char ged. Founded in 1981, purolite is a leading manufacturer of ion exchange, catalyst, adsorbent and. An understanding of these principles will enable the separation power of ion exchange chromatography iex to be fully appreciated.
Ion exchange in analytical chemistry provides a broad survey of the important role that ion exchange can and should play in chemical analysis. Their analysts see increased nuclear power demand and stringent environmental. This process is often used in softening water as well as in separating radioisotopes in water. All natural waters contain some foreign substances, usually in small amounts. Transfer1gramofcationexchangeresintoa150or250mlbeaker. Live calculations, functions and calculation procedures on. Since dozens of factors can impact the productivity of the system, the cadix system design software program from dow offers precise design recommendations to optimize system performance. Steps to design an ion exchange resin system accurate system design is critical to getting the most from a water treatment system. Information on properties of ionexchange resins is supplied to users in two forms. Jourizal of chromatography, 154 1978 175191 0 mevier scientific publishirv company, amsterdam printed in the netherlands ceiromi 10,903 calculation of retention volumes in ion excilange chromatographiyr using the gradient elution technique separations on cation exchange resins l ikcz8dy institute of analytical chemistry university of chemical enghteermg, veszprem hungary first. Ion exchange in the ion exchange process an insoluble resin removes ions of either positive charge or negative charge from solution and releases other ions of equivalent charge into solution. The power of chromatography 9 comes from its ability to separate a mixture of compounds, or analytes, and. This process can be reversed, as the ions within the solution can undergo exchange.
Principles of ion exchange this chapter provides a general introduction to the theoretical principles that underlie every ion exchange separation. So if you dont want to have chloride in your water you have to stop the ion exchange system or if you have a duplex system you can switch to the other column available and regenerate the column that is saturated with the absorbed ions. The cycle time for each cation anion pairing is determined by the water analysis, flow rate and number of streams. Puredesign is an innovative ion exchange simulation program that helps facilitate design and simulation of ion exchange commonly used in. A simple set of calculations using a microsoft excel spreadsheet can help students determine ionexchange equilibrium parameters, essential for the design of industrial equipment. The ion exchange water softening process can remove nearly all calcium and magnesium from source water. View enhanced pdf access article on wiley online library html view download pdf for offline viewing. Ions electrically charged atoms or molecules cations and anions can have one or more charges mostly 1 to 3, and can be made of one or more atoms monoatomic ions.
How to calculate ion exchange capacity theoritically. For example, in softening processes, calcium and magnesium ions hardness are. All large scale applications for ion exchange resins. The calculations below are based on orvilles ionexchange experiments between an aqueous nak chloride solution and alkali feldspars of the sanidinehigh albite series, and do not take into account his twofeldspar assemblages as such. Nernstplanck equations of ionic motion, which take into account the effect of the electric forces diffusion potential within the system. Based on the plan of action, three main parameters should be considered in experiments. Resources ion exchange resin manufacturer purolite.
I have used borosilicate glass particles which have coating of tio2 nanoparticles. History, introduction, and kinetics of ion exchange materials. Softener operation basic ion exchange process thumb rules of designing a softener step 1 to select resin quantity ltrs for a particular hardness ppm for a particular output m3 per regeneration per hour based on regeneration level 160 gmltr, ion exchange capacity 55, tds limit 1500 ppm refer table 1 resin quanitity load ppm as caco3 flow time ex. Pdf ion exchange resins encompass one of the most important scientific developments of the 20 th century. In the last 20 years, geochemical modeling based on equilibrium and irreversible thermodynamics has become a well. This nebguide focuses on the ion exchange softening process which remains the most commonly used technique for managing hard water in residential settings. Condensation polymers are those in which the molecular formula of the mesomer lacked. This book focuses on the plateequilibrium theory of chromatography, which is less difficult theoretically than the masstransfer theory. I treated the surface of these glass particles with conc. The document also goes over basic terminology and calculations used to determine the amount of brine needed during regeneration.
Ion exchange chromatography wolfson centre home page. Ion exchange water treatment budapest university of. Ion exchange as a physical process during ion exchange the ions being exchanged are reversibly removed from the wastewater and transferred to the ion exchanger this means that ion exchange is a physical separation process in which the ions exchanged are not chemically altered since the chemical characteristics of the ions. A synthetic zeolite resin will be packed in shells with diameter of 5 ft. Ion exchange materials are capable of exchanging soluble cations and ions with electrolyte solutions and transferring them into sludge. Silversodium ion exchange dynamics in lta zeolite membranes. Ion exchange calculator 2 this calculator is under construction. The capacity for exchange of an ion exchange resin is given in terms of meqml resin.
We will not reply individually to sales promotions, slander, questionnaires, surveys, requests for donations, and any other inquiries, opinions, requests not directly related to group business. As you can see from the calculations of v max the breakthrough occurs first for chloride when 60 l of water has been treated. Ion exchange usually describes a processes of purification of aqueous solutions using solid polymeric ion exchange resin. Rohm and haas ion exchange ion exchange introduction 1 fd sep 2008 ion exchange for dummies an introduction water water is a liquid.
Columns of cationexchange resin are used, and the solutions are maintained sufficiently. Equilibrium parameters are evaluated from experimental isotherms obtained from different zeolites using the actionlaw model by means of nonlinear curve fitting. Ion exchange is pr obably the most fr equently used chr omatographic technique for the separation and purification of pr oteins, polypeptides, nucleic acids, polynucle otides, and other char ged biomolecules 1. Chapter 1 2 3 introduction, chromatography theory, and.
First order kinetics was assumed for ion exchange rates and the ion concentration in and out of the membrane, temperature and crystal thickness were considered as the principal parameters affecting the release rate. Calculate the concentrations of cations and anions expressed as caco3 in the. Calculation of retention volumes in ionexchange chromatography using the gradient elution technique. Both chemists and biochemists have routinely employed this technique for the purification of. Because of their high ion exchange capacity, silver exchanged lta aglta zeolites can be incorporated in polymeric materials as antibacterial agents for various purposes such as preventing biofouling in water treatment membranes due to the formation of microorganisms like bacteria, algae. Ion exchange design procedures marmara universitesi. Calculating cation exchange capacity and the percent base saturation the cation exchange capacity cec is a term used to describe the holding capacity of a particular soil for positivelycharged elements cations. From the exchange data it is possible to calculate the gibbs energv of mixing of sanidine at several.
The mobile counter ions are replaced by other ions from the solution with the same charge donnan, 1911. An ion exchange process is to be used to soften water at the rate of 500 gpm. Applications presents an overview of the numerous industrial applications of ion exchange materials in particular, this volume focuses on the use of ion exchange materials in various fields including chemical and biochemical separations, water purification, biomedical science, toxic metal recovery and concentration, waste water treatment, catalysis, alcohol. As a rule, a user runs a program installed on a disk or downloaded from the. These brochures give an overview of purolite packaging options, which include bags, boxes, drums, kegs, and tankers. The resin has an exchange capacity of 320 kilograins of caco 3 per ft when regenerated at the 3rate of 15 ib of salt per ft. Fundamentals and applications of ion exchange springerlink. Ionexchange calculations using spreadsheets springerlink. Applications presents an overview of the numerous industrial applications of ionexchange materials in particular, this volume focuses on the use of ionexchange materials in various fields including chemical and biochemical separations, water purification, biomedical science, toxic metal recovery and concentration, waste water treatment, catalysis, alcohol.
This chapter provides a basic understanding of the ion exchange process, ion. The basic process of chromatography using ion exchange can be represented in 5 steps as. Please understand that we may not be able to respond to all inquiries. Comparison of calculated and measured isotherms of calcium ion exchange by zeolite a, t 22c, 1 h. Information on the ionexchange resin on the internet figure 1 shows a part of technical process bulletin of ionexchange resin amberjet 1200 na produced by rohm and haas1 available on the internet as a pdffile, which one can read and print but cant calculate by it. Ion exchange is the process through which ions in solution are. Ion exchange is the chemical reaction that exists between a solution and an insoluble solid. Ion exchange is used for both analytical and preparative purposes in the laboratory, the analytical uses being the more common. In literature, the important parameters also include temperature of water, particle size of ion. The technique of ion exchange chromatography is based on this interaction.
Purolite ion exchange design calculation program download free. For this reason, natural water does not exist as a chemically pure substance. It helps to simulate the influence on performance and quality at different parameters like salinity and ionic composition of the water, temperature, organic. The calculations below are based on orvilles ion exchange experiments between an aqueous nak chloride solution and alkali feldspars of the sanidinehigh albite series, and do not take into account his twofeldspar assemblages as such. An important use of ionexchange chromatography is in the routine analysis of amino acid mixtures. The raw water has total hardness of 100 mgl as caco 3. Water treatment calculations updated membrane ion exchange. Ionexchange reaction ionexchange reaction applications of ion exchange. In a near neutral soil, calcium remains adsorbed on colloidal particle.
Ion exchange is an effective, versatile means of conditioning boiler feedwater. Ionexchange membranes, like the resins, have fixed ion functional groups and oppositely charged. Charge ion exchange chromatography iex size size exclusion chromatography sec, also called gel. Ion exchange resin can be classified on the basis of functional groups as anion exchange resin, cationic exchange resin and chelating exchange resin. The ion exchange dynamics between the lta crystal and the electrolyte solution was followed by long md simulations. Environmental ion exchange principles and design fundamental. Practical aspects of performing a separation are covered in chapter 2. Only a few general recommendations to ensure that an ion exchange system is designed economically and to achieve good performance, and a simple, but detailed example. May 06, 2016 live calculations, functions and calculation procedures on.